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Triethylamine CAS#121-44-8

Triethylamine CAS#121-44-8
Iupac Name:N,N-diethylethanamine
CAS No.: 121-44-8
Molecular Weight:101.19000
Introduction:
Triethylamine (C6H15N) is an organic compound. At room temperature, triethylamine appears as a colorless liquid with a strong, fishy odor. This compound belongs to the class of tertiary amines, which are derivatives of ammonia where all three hydrogen atoms have been replaced by alkyl groups. Specifically, in the case of triethylamine, these alkyl groups are ethyl groups. As such, it exhibits characteristic properties of amines, including basicity and nucleophilicity, making it an important reagent in various chemical processes.

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PRODUCT DESCRIPTION

PropertyValue
Density0.8±0.1 g/cm³
Boiling Point90.5±8.0 °C at 760 mmHg
Melting Point-115 °C
Molecular FormulaC₆H₁₅N
Molecular Weight101.190
Flash Point-6.7±0.0 °C
Exact Mass101.120445
PSA3.24000
LogP1.66
Vapour Density3.5 (vs air)
Vapour Pressure56.1±0.2 mmHg at 25°C
Index of Refraction1.412
InChIKeyZMANZCXQSJIPKH-UHFFFAOYSA-N
SMILESCCN(CC)CC
StabilityStable. Extremely flammable. Readily forms explosive mixtures with air. Incompatible with strong oxidizing agents, strong acids, ketones, aldehydes, halogenated hydrocarbons.
Water Solubility133 g/L (20 °C)

Use and Manufacturing

1 DefinitionChEBI: A tertiary amine that is ammonia in which each hydrogen atom is substituted by an ethyl group.

2 Environmental FatePhotolytic. Low et al. (1991) reported that the photooxidation of aqueous tertiary aminesolutions by UV light in the presence of titanium dioxide resulted in the formation of ammoniumand nitrate ions.Chemical/Physical. Triethylamine reacted with NOx in the dark to form diethylnitrosamine. Inan outdoor chamber, photooxidation by natural sunlight yielded the following products:diethylnitramine, diethylformamide, diethylacetamide, ethylacetamide, diethylhydroxylamine,ozone, acetaldehyde, and peroxyacetyl nitrate (Pitts et al., 1978).

3 Methods of Manufacturing1. Available with ethanol and ammonia methy. The ethanol and liquid ammonia are preheated in a preheater (150 ± 5 ℃) in the presence of hydrogen gas and then fed into a first reactor (190 ± 2 ℃) equipped with a copper-nickel-clay catalyst and The second reactor (165 ± 2 ℃) synthesis, resulting in a ethylamine; diethylamine; triethylamine mixture, after condensation, and then by ethanol spray absorption triethanolamine crude, the final separation; dehydration and fractionation , Collecting 88-90 ℃ distillate triethylamine. (99%) 150 standard cubic meters, t; hydrogen gas (99%), the standard consumption of raw materials: ethanol (95%) 2300kg, t; Refining method: often contain ethylamine, diethylamine and acetaldehyde and other impurities, generally refined by fractional distillation. To remove traces of primary and secondary amines, acetic anhydride, benzoic anhydride or phthalic anhydride may be added and refluxed after fractionation. The distillate may be dried with activated alumina or solid potassium hydroxide and then distilled. Other purification methods are: the triethylamine into hydrochloride, and then ethanol recrystallization, to the melting point of 254 ℃, with sodium hydroxide aqueous solution to free the triethylamine, the solid potassium hydroxide after drying, In the presence of sodium in the nitrogen stream was distilled pure.
2. In the presence of oxygen, ethanol and ammonia in copper, nickel, clay catalyst in the presence of heating synthesis reaction, generating one, Di- and triethylamine mixtures. The mixture is condensed, extracted and absorbed to obtain crude product. Crude and then separated, standing layered, dehydration, distillation that was the product.
3. Mix ethanol (kg), liquid ammonia (kg) and hydrogen (standard m3) in a proportion of 23:50:15 and then preheat to 145-155 ℃, then feed the first reactor with copper nickel clay catalyst (About 190 ℃) and the second reactor (about 165 ℃) to form a mixture of ethylamine, diethylamine and triethylamine, condensed and condensed, collecting 88 ~ 90 ℃ distillate triethylamine.
4. Synthesis: Ethyl chloride and ammonia from heating under pressure derived.

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